Emergent ferromagnetism in ZnO/Al2O3 core-shell nanowires: Towards oxide spinterfaces

Emergent ferromagnetism in ZnO/Al2O3 core-shell nanowires: Towards oxide spinterfaces

Emergent ferromagnetism in ZnO/Al2O3 core-shell nanowires: Towards oxide spinterfaces
G.Z. Xing, D.D. Wang, C.-J. Cheng, M. He, S. Li, T. Wu
Applied Physics Letters, Volume 103, Issue 2, Article number 022402, (2013)
G.Z. Xing, D.D. Wang, C.-J. Cheng, M. He, S. Li, T. Wu
Core-shell nanowires, High temperature measurement, Magnetic orders, Nanoscale architectures, Room-temperature ferromagnetism, Structural defect, Thermally stable, Wide band gap
2013


We report that room-temperature ferromagnetism emerges at the interface formed between ZnO nanowire core and Al2O3 shell although both constituents show mainly diamagnetism. The interface-based ferromagnetism can be further enhanced by annealing the ZnO/Al2O3 core-shell nanowires and activating the formation of ZnAl2O4 phase as a result of interfacial solid-state reaction. High-temperature measurements indicate that the magnetic order is thermally stable up to 750 K. Transmission electron microscopy studies reveal the annealing-induced jagged interfaces, and the extensive structural defects appear to be relevant to the emergent magnetism. Our study suggests that tailoring the spinterfaces in nanostructure-harnessed wide-band-gap oxides is an effective route towards engineered nanoscale architecture with enhanced magnetic properties.




10.1063/1.4813217

00036951